The inventory column is the total of item ledger entries, the bin contents is the total of warehouse entries. You need to look at both and see why they are out of sync. Have all your entries been posted? It is possible to update one but not the other.
Hi, don't know from which version there is an ADJUSTMENT warehouse zone (lost&found section). And hope I'm not wrong - these entries are correcting only the WMS stock, not the item ledgers ...
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https://msdn.microsoft.com/en-us/library/hh173795(v=nav.90).aspx