From version 5.0 there is a codeunit 400 SMTP Mail that is used to send mail through SMTP. Take a look at that. The SMTP setup is done at Form 409. If you're using a previous version there is a tips somewhere on Mibuso on how to use named objects in a previous version. Search for it.
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if u have..
Setup SMTP.
-Mohana
http://mohana-dynamicsnav.blogspot.in/
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I have SMTP server, but how to configure or what code should I write to
send an email from NAV through SMTP
Senior Consultan